Search
Now showing items 1-5 of 5
New active ruthenium(II) complexes based N3,N3?-bis(diphenylphosphino)-2,2?-bipyridine-3,3?-diamine and P,P?-diphenylphosphinous acid-P,P?-[2,2?-bipyridine]-3,3?-diyl ester ligands for transfer hydrogenation of aromatic ketones by propan-2-ol
(Elsevier Science Sa, 2009)
The dimeric starting material [Ru(eta(6)-p-cymene)(mu-Cl)Cl](2) reacts with N3,N3'-bis(diphenylphosphino)-2,2'-bipyridine-3,3'-diamine, 1 and P,P'-diphenylphosphinous acid-P,P'-[2,2'-bipyridine]-3,3'-diyl ester, 2 ligands ...
Synthesis and characterizations of N,N,N?,N?-tetrakis (diphenylphosphino)ethylendiamine derivatives: Use of palladium(II) complex as pre-catalyst in Suzuki coupling and Heck reactions
(Elsevier Science Sa, 2009)
Oxidation of N,N,N',N'-tetrakis(diphenylphosphino)ethylendiamine (1) with elemental sulfur and selenium gives the corresponding sulfide and selenide, respectively, [(Ph2P(E))(2)NCH2CH2N(P(E)Ph-2)(2)] (E: S 1a, Se 1b). ...
Synthesis and characterization of new bis(diphenylphosphino)aniline ligands and their complexes: X-ray crystal structure of palladium(II) and platinum(II) complexes, and application of palladium(II) complexes as pre-catalysts in Heck and Suzuki cross-coupling reactions
(Pergamon-Elsevier Science Ltd, 2009)
Two new bis(diphenylphosphino)isopropylphenylamines, (PPh2)(2)N-C6H4-CH(CH3)(2), having the isopropyl substituent at the carbon atom 2 (1) or 4 (2), were prepared by the aminolysis of chlorodiphenylphosphine with isopropyl ...
Ruthenium-catalyzed transfer hydrogenation of aromatic ketones with aminophosphine or bis(phosphino)amine ligands derived from isopropyl substituted anilines
(Pergamon-Elsevier Science Ltd, 2010)
A series of new highly active Ru(II) complexes with two new (N-diphenylphosphino)isopropylanilines, having an isopropyl substituent at carbon 2- (1) or 2,6- (2) and two new bis(diphenylphosphino)isopropylanilines, having ...
Ruthenium complexes of aminophosphine ligands and their use as pre-catalysts in the transfer hydrogenation of aromatic ketones: X-ray crystal structure of thiophene-2-(N-diphenylthiophosphino)methylamine
(Pergamon-Elsevier Science Ltd, 2011)
Reaction of thiophene-2-methylamine with one or two equivalents of PPh2Cl in the presence of NEt3, proceeds in thf to give thiophene-2-(N-diphenylphosphino)methylamine, la and thiophene-2-(N, N-bis(diphenylphosphino))methylamine, ...
