Browsing by Author "Elmas, Gamze"
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The comparative reactions of 2-cis-4-ansa and spiro cyclotetraphosphazenes with difunctional ligands: Structural and stereogenic properties, electrochemical, antimicrobial and cytotoxic activity studies
Okumuş, Aytuğ; Elmas, Gamze; Kılıç, Zeynel; Binici, Arzu; Ramazanoğlu, Nagehan; Açık, Leyla; Çoşut, Bünyemin; Güzel, Remziye (Wiley, 2021)In this study, two kinds of compounds, namely, mono-ferrocenyl-2-cis-4-dichloro-ansa- (2,4-ansa; 3) and mono-ferrocenyl-spiro- (spiro; 4) hexachlorocyclotetraphosphazenes, were obtained by the Cl replacement reaction of ... -
Phosphorus-nitrogen compounds. Part 35. Syntheses, spectroscopic and electrochemical properties, and antituberculosis, antimicrobial and cytotoxic activities of mono-ferrocenyl-spirocyclotetraphosphazenes
Okumus, Aytug; Elmas, Gamze; Cemaloglu, Resit; Aydin, Betul; Binici, Arzu; Simsek, Hulya; Acik, Leyla (Royal Soc Chemistry, 2016)The reactions of octachlorocyclotetraphosphazene, N4P4Cl8, with N-alkyl-N-mono-ferrocenyldiamines, FcCH(2)NH(CH2)(n)NHR1 [n = 2, Fc = ferrocene, R-1 = Me (1); n = 2, R-1 = Et (2) and n = 3, R-1 = Me (3)], led to the formation ... -
Phosphorus-nitrogen compounds. part 38. Syntheses, characterizations, cytotoxic, antituberculosis and antimicrobial activities and DNA interactions of spirocyclotetraphosphazenes with bis-ferrocenyl pendant arms
Elmas, Gamze; Okumuş, Aytuğ; Cemaloğlu, Reşit; Kılıç, Zeynel; Çelik, Süheyla Pınar; Açık, Leyla; Tunalı, Beste Cağdaş (Elsevier Science Sa, 2017)The reactions of N4P4Cl8 (1), with two equimolar amounts of N-(1-ferrocenylmethyl)-N-methyl-propylenediamine gave the monoferrocenyl-spiro (as a byproduct), bisferrocenyl-2-trans-6-dispiro (2) and bisferrocenyl-2-cis-6-dispiro ... -
Phosphorus-nitrogen compounds. Part 42. The comparative syntheses of 2-cis-4-ansa(N/O) and spiro(N/O) cyclotetraphosphazene derivatives: spectroscopic and crystallographic characterization, antituberculosis and cytotoxic activity studies
Binici, Arzu; Okumus, Aytug; Elmas, Gamze; Kilic, Zeynel; Ramazanoglu, Nagehan; Acik, Leyla; Simsek, Hulya (Royal Soc Chemistry, 2019)The reaction of N4P4Cl8 (1) with one equimolar amount of the sodium salt of an N/O donor-type bidentate ligand (2) afforded two kinds of derivatives, namely, mono-ferrocenyl-2-cis-4-dichloro-ansa- (2,4-ansa; 3) and ... -
Phosphorus-nitrogen compounds. Part 65. Novel diansa-spiro-cyclotetraphosphazenes: synthesis, characterization, bioactivity and electrochemical properties, and dye-sensitized solar cell fabrication studies
Mutlu, Gurcu; Okumus, Aytug; Elmas, Gamze; Kilic, Zeynel; Guzel, Remziye; Sabah, Busra Nur; Acik, Leyla (Royal Soc Chemistry, 2022)In this investigation, the substitution reaction of octachlorocyclotetraphosphazene, N4P4Cl8 (tetramer, OCCP, 1), with sodium 3-(N-ferrocenylmethylamino)-1-propanoxide (L1) was found to yield the compounds, 2,4-ansa-(2) ... -
Phosphorus-nitrogen compounds: Part 60: Synthesis of hexaminomonoferrocenyl-spiro(N/O)cyclotetraphosphazenes: Spectral and electrochemical properties, tuning of redox feature, and antituberculosis activity
Binici, Arzu; Elmas, Gamze; Okumus, Aytug; Guzel, Remziye; Simsek, Hulya; Kilic, Zeynel (Taylor & Francis Ltd, 2023)In the present investigation, the condensation reaction of octachlorocyclotetraphosphazene, N4P4Cl8 (1) (tetramer, OCCP), with sodium 3-(N-ferrocenylmethylamino)-1-propanoxide (L) resulted in the formation of the starting ...