Browsing by Author "Binbay, Nil Ertekin"
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Biological assays and theoretical density functional theory calculations of Rh(I), Ir(III), and Ru(II) complexes of chiral phosphinite ligand
Rafikova, Khadichakhan; Binbay, Nil Ertekin; Meriç, Nermin; Kerimkulova, Aygül; Zazybin, Alexey; Binbay, Veysel; Okumuş, Veysi; Kayan, Cezmi; Işık, Uğur; Aydemir, Murat (Wiley, 2020)Four metal complexes, IL-OPPh2-Ru-p-cymene (3), IL-OPPh2-Ru-benzene (4), IL-OPPh2-Ir-Cp* (5), IL-OPPh2-Rh-COD (6), have been evaluated for in vitro antioxidant activity such as 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical ... -
Biological assays, electrochemical behavior, and theoretical DFT calculations of Ru(II) complexes of chiral phosphinite based based on ?-amino alcohols: Transfer hyrogenation of ketones using a HCOOH/Et3N mixture
Khadichakhan, Rafikova; Meriç, Nermin; Binbay, Nil Ertekin; Okumuş, Veysi; Sever, M. Şerif; Belyankova, Yelizaveta; Aydemir, Murat (Elsevier B.V., 2024)Synthesis of two phosphinite ligands based on β-amino alcohols, in high yields has been demonstrated. When we treated [Ru(arene)(μ-Cl)Cl]2 {arene:p-cymene,benzene} with chelating phosphinite ligands, we obtained neutral ... -
Bloch denklemlerinin fortran'da nümerik yöntemlerle çözümü
Binbay, Nil Ertekin (Dicle Üniversitesi, Fen Bilimleri Enstitüsü, 2001)Bu çalışmada NMR' in temel denklemlerinden olan " Bloch Denklemleri " nin nümerik yöntemlerle çözümü yapılmıştır. Bunun için önce probleme uygun nümerik algoritmalar ve yöntemler incelenmiş ve tanıtılmıştır. Bloch ... -
Comparative dft study of a ruthenium complex
Binbay, Nil Ertekin (Turkish Chemical Society, 2020)A comparative density functional theory (DFT) study of the Ruthenium complex (pentamethylcyclopentadienyl)(diisopropylmethylphosphine)(chloro)(trichlorosilyl)ruthenium hydride is reported. The molecule contains a ruthenium ... -
Comparison of LANL2DZ and SBKJC Basis Sets, over DFT Calculations of a Typical Half-Sandwich Ruthenium Complex
Binbay, Nil Ertekin (Maik Nauka/Interperiodica/Springer, 2022)As number of computational studies related transition metals have been increasing, the LANL2DZ basis set become one of the most popular basis set for transition metal complexes among others. The reason for that is mostly ... -
DFT investigation of transtion metals arene compounds with functionalized ionic liquid
Meriç, Nermin; Binbay, Nil Ertekin; Kayan, Cezmi; Binbay, Veysel; Aydemir, Murat (INESEG Yayıncılık, 2022)Electrochemical properties and theoretical DFT computations have been carried out for the cationic parts of complexes of ionic liquid-based phosphinite, (1A-3A). The effects of the chemical structures of cationic parts of ... -
Electrical and photoelectrical characterization of organic-inorganic heterostructures based on Ru-N-heterocyclic carbene complexes
Yasar, Sedat; Cekirdek, Suzan; Binbay, Nil Ertekin; Tombak, Ahmet; Ocak, Yusuf Selim; Arslan, Nevin; Baysal, Akin (Elsevier Gmbh, 2018)1,3-Bis(2-morpholinethyl)benzimidazoliumtrichlorido(eta(6)-p-cymene)-ruthenate(11), 2, was synthesized and characterized by NMR spectroscopy and micro analysis. The organic -inorganic heterojunctions were fabricated by ... -
New functional chiral P-based ligands and application in ruthenium-catalyzed enantioselective transfer hydrogenation of ketones
Meric, Nermin; Kayan, Cezmi; Gurbuz, Nevin; Karakaplan, Mehmet; Binbay, Nil Ertekin; Aydemir, Murat (Pergamon-Elsevier Science Ltd, 2017)Metal-catalyzed asymmetric transfer hydrogenation is a powerful and practical method for the reduction of ketones to produce the corresponding secondary alcohols, which are valuable building blocks in the pharmaceutical, ... -
Transition metals of arene derivatives with functionalized ionic liquid: DFT investigation, biological applications and electrochemical behavior of complexes
Rafikova, Khadichakhan; Meric, Nermin; Guzel, Remziye; Arslan, Nevin; Binbay, Nil Ertekin; Kayan, Cezmi; Okumus, Veysi (Elsevier Science Sa, 2022)Mononuclear transition metal complexes based on ionic liquid have been prepared and characterized in detail. The biological properties of the three complexes were evaluated using radical scavenging activity, reducing power, ... -
Well designed iridium-phosphinite complexes: Biological assays, electrochemical behavior and density functional theory calculations
Khadichakhan Rafikova; Meriç, Nermin; Binbay, Nil Ertekin; Okumuş, Veysi; Erdem, Kemal; Belyankova, Yelizaveta; Güzel, Remziye (Elsevier B.V., 2024)Mononuclear phosphinite Iridium complexes based on ferrocene group have been prepared and characterized by various spectroscopic techniques. The complexes were subjected to cyclic voltammetry studies in order to determine ...
