Temel, HamdiIlhan, Salih2024-04-242024-04-2420081386-14251879-2731https://doi.org/10.1016/j.saa.2007.05.041https://hdl.handle.net/11468/15998The new five macrocyclic ligands were synthesized by reaction of 2,6-diaminopyridine and various dialdehydes. Then, their copper(II) perchlorate complexes were synthesized by template effect by reaction of 2,6-diaminopyridine, Cu(ClO4)(2 center dot)6H(2)O and aldehydes. The ligands and their complexes have been characterized by elemental analysis, IR, H-1 and C-13 NMR, UV-vis spectra, magnetic susceptibility, conductivity measurements, mass spectra. All complexes are diamagnetic and binuclear. The diamagnetic behaviour of the binuclear complexes may be explained by a very strong anti-ferromagnetic interaction in the Cu-Cu pair. (C) 2007 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessMacrocyclic Schiff BaseCopper(Ii) Complexes Of Macrocyclic Schiff Base2,6-DiaminopyridineArticle693896903WOS:0002547701000312-s2.0-430490874071760421210.1016/j.saa.2007.05.041Q1Q3