Baysal, AkinAydemir, MuratDurap, FeyyazOzkar, SaimYildirim, Leyla TatarOcak, Yusuf Selim2024-04-242024-04-2420150277-5387https://doi.org/10.1016/j.poly.2014.12.046https://hdl.handle.net/11468/15962The ruthenium(B) complex [Ru(bpy)(2)L](PF6)(2), where bpy is 2,2'-bipyridine and L is 1,5-dihydro-2-H-cyclopenta[1,2-b:5,4-b']dipyridine-2-one, was synthesized from the reaction of cis-Ru(bpy)(2)Cl-2 center dot 2H(2)O with L, and isolated as the hexafluorophosphate salt. The structure of L was unequivocally elucidated by single-crystal X-ray diffraction analysis. The new ruthenium(II) complex was thoroughly characterized by H-1 and C-13 NMR spectroscopy, along with FTIR, UV-Vis and LC MS/MS Triple Quadrupole Mass spectroscopy and elemental analysis. The catalytic activity of [Ru(bpy)(2)L](PF6)(2) was tested in the transfer hydrogenation of various ketones in 2-propanol as both the solvent and hydrogen donor. The usage of [Ru(bpy)(2)L](PF6)(2) for the formation of a dye sensitized solar cell is also presented. (C) 2015 Elsevier Ltd. All rights reserved.eninfo:eu-repo/semantics/closedAccessN LigandCatalystTransfer HydrogenationDsscX-RayArticle895561WOS:0003519656000082-s2.0-8492213572010.1016/j.poly.2014.12.046Q2Q2