Meriç, NerminGümgüm, BahattinBiricik, NerminAzizoğlu, Sevil ŞekerÖzgen, ZeynepKayan, Cezmi2024-04-242024-04-2420151300-05271303-6130https://search.trdizin.gov.tr/yayin/detay/259140https://hdl.handle.net/11468/27394A series of new aminophosphines [Ph 2 PHN-C 6 H 4 -R, where R = o -SH ( 4a ), m -SH ( 4b) or p -SH ( 4c )] were readily synthesized from cheap starting materials by the phosphorylation reaction of o , m , and p -aminothiophenols with Ph 2 PCl in the presence of triethyl amine. The new compounds were characterized by NMR and IR spectroscopy and microanalysis. In addition, aminophosphine ligands{palladium systems were investigated as precatalysts in C{C coupling reactions. Compounds 4b and 4c were proved to be excellent catalysts for Suzuki and Heck cross-coupling reactions.eninfo:eu-repo/semantics/openAccessArticle39612571264259140