Novel half-sandwich η5-Cp *-rhodium(III) and η5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketones

Ok, FatihAydemir, MuratDurap, FeyyazBaysal, Akın2024-04-242024-04-242014Ok, F., Aydemir, M., Durap, F. ve Baysal, A. (2014). Novel half-sandwich η5-Cp *-rhodium(III) and η5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketones. Applied Organometallic Chemistry, 28(1), 38-43.0268-26051099-0739https://doi.org/10.1002/aoc.3068https://hdl.handle.net/11468/13962https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.3068Two new half-sandwich (5)-Cp*-rhodium(III) and (5)-Cp*-ruthenium(II) complexes have been prepared from corresponding bis(phosphino)amine ligands, thiophene-2-(N,N-bis(diphenylphosphino)methylamine) or furfuryl-2-(N,N-bis(diphenylphosphino)amine). Structures of the new complexes have been elucidated by multinuclear one- and two-dimensional NMR spectroscopy, elemental analysis and IR spectroscopy. These Cp*-rhodium(III) and Cp*-ruthenium(II) complexes bearing bis(phosphino)amine ligands were successfully applied to transfer hydrogenation of various ketones by 2-propanol. Copyright (c) 2013 John Wiley & Sons, Ltd.eninfo:eu-repo/semantics/closedAccessBis(Phosphino)AmineCp*RhodiumRutheniumTransfer hydrogenationNovel half-sandwich η5-Cp *-rhodium(III) and η5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketonesNovel half-sandwich ?5-Cp *-rhodium(III) and ?5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketonesArticle2813843WOS:0003282266000052-s2.0-8489054973210.1002/aoc.3068Q1Q1