Subasi, ElifTemel, Hamdi2024-04-242024-04-2420071553-31741553-3182https://doi.org/10.1080/15533170601187409https://hdl.handle.net/11468/17019The hitherto unknown complexes, [M(CO)(4)(eta(2)-H2L)], [M = Cr; 1, Mo; 2, W; 3]; fac-[Re(CO)(3)Br(eta(2)-H2L)], 4 and [(eta(5)-C5H5)Mn(CO)Br(eta(2)-H2L)], 5 have been synthesized by the photochemical reactions of VIB and VIIB metal carbonyls [M(CO)(6)] [M = Cr, Mo, W], Re(CO)(5)Br and (eta(5)-C5H5) Mn(CO)(3) with chiral Schiff base N,N'-bis-(2-hydroxynaphthalene-1-carbaldehydene)-(1R,2R)-(-)-diaminocyclohexane (H2L) in THF and characterized by elemental analyses, FTIR, H-1-NMR and mass spectra. The spectroscopic studies show that H2L ligand is coordinated to the central metal as a bidentate ligand coordinating via its imine nitrogens (C=N) in 1-5.eninfo:eu-repo/semantics/closedAccessN,N-Bis-(2-Hydroxynaphthalene-1-Carbaldehydene)-(1r,2r)-(-)-DiaminocyclohexaneMetal CarbonylsSchiff BaseArticle3728589WOS:0002457877000032-s2.0-3394719886510.1080/15533170601187409N/AQ3