Rafikova, KhadichakhanBaysal, AkınMeriç, NerminZazybin, AlexeyKayan, CezmiIşık, UğurDurap, FeyyazAydemir, Murat2023-04-052023-04-052022Rafikova, K., Baysal, A., Meriç, N., Zazybin, A., Kayan, C., Işık, U. ve diğerleri. (2022). Ketone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand. Journal of Coordination Chemistry, 75(3-4), 493-506.0095-89721029-0389https://www.tandfonline.com/doi/full/10.1080/00958972.2022.2054339https://hdl.handle.net/11468/11620Reaction of (+/-)-1-(2-furyl) ethanol with an equivalent Ph2PCl in the presence of Et3N proceeds in dry toluene under an argon atmosphere to give 1-(furan-2-yl)ethyl diphenylphosphinite (1) in good yield. Mononuclear complexes [dichloro(eta(6)-p-cymene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (2), [dichloro(eta(6)-benzene)(1-furan-2-ylethyl diphenylphosphinite)ruthenium(II)] (3), [chloro(eta(4)-1,5-cyclooctadiene)(1-furan-2-ylethyl diphenylphosphinite)rhodium(I)] (4) and [dichloro(eta(5)-pentamethylcyclopentadienyl)(1-furan-2-ylethyl diphenylphosphinite)iridium(III)] (5) were synthesized and characterized by microanalysis, infrared, MS, and NMR spectroscopies. The complexes are employed as catalysts in transfer hydrogenation of aromatic ketones. The complexes catalyzed reduction of a variety of aromatic ketone substrates bearing electron-withdrawing or donating substituents with very high conversion rates (up to 99%); 5 was the most efficient catalyst for the transfer hydrogenation of ketones.eninfo:eu-repo/semantics/closedAccessTransfer hydrogenationIridiumKetonePhosphinite ligandTransition metalArticle753-4493506WOS:0007911321000012-s2.0-8513178057010.1080/00958972.2022.2054339Q3Q3