Biricik, NerminKayan, CezmiGümgüm, Bahattin2024-04-242024-04-242014Biricik, N., Kayan, C. ve Gümgüm, B. (2014). P-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines. Helvetica Chimica Acta, 97(8), 1158-1164.0018-019X1522-2675https://doi.org/10.1002/hlca.201400074https://hdl.handle.net/11468/14042https://onlinelibrary.wiley.com/doi/10.1002/hlca.201400074The reaction of tertiary amine functionalized phosphines with aromatic and aliphatic aldehydes gives insertion of carbon fragments into the P-III-N bonds or P-III-N bond cleavage. The reaction of bis(diphenylphosphino) amines, la lc, with two equiv. of aldehydes in toluene afforded the P-III-N bond inserted products, 2a-4a, 4b-6b, and 3c-5c, in moderate-to-good yield. The products were characterized by IR, H-1- and P-31-NMR spectroscopy and elemental analysis.eninfo:eu-repo/semantics/closedAccess[No Keyword]Article97811581164WOS:0003412950000152-s2.0-8490733949110.1002/hlca.201400074Q3Q3