Karakaş, Duygu ElmaDurap, FeyyazAydemir, MuratBaysal, Akın2024-04-242024-04-242016Karakaş, D. E., Durap, F., Aydemir, M. ve Baysal, A. (2016). Synthesis, characterization and first application of chiral C2-symmetric bis(phosphinite)-Pd(II) complexes as catalysts in asymmetric intermolecular Heck reactions. Applied Organometallic Chemistry, 30(4), 193-198.0268-26051099-0739https://doi.org/10.1002/aoc.3416https://hdl.handle.net/11468/13969https://onlinelibrary.wiley.com/doi/10.1002/aoc.3416A series of new chiral C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes have been synthesized and for the first time used as catalysts in the palladium-catalysed asymmetric intermolecular Heck coupling reactions of 2,3-dihydrofuran with iodobenzene or aryl triflate. Under optimized conditions, products were obtained with high conversions and moderate to good enantioselectivities. The new C-2-symmetric bis(phosphinite) ligands and their palladium(II) complexes were characterized using multinuclear NMR and Fourier transform infrared spectroscopies and elemental analysis. Copyright (c) 2015 John Wiley & Sons, Ltd.eninfo:eu-repo/semantics/closedAccessPalladium(Ii)C-2 symmetryPhosphiniteAsymmetric heck couplingArticle304193198WOS:0003729247000042-s2.0-8495343281910.1002/aoc.3416Q1Q2