Özbey, SKaynak, FBTogrul, MDemirel, NHosgören, H2024-04-242024-04-2420031388-31271573-1111https://doi.org/10.1023/A:1023042119365https://hdl.handle.net/11468/16420A new complex of a chiral monoaza-crown ether, [R-(-)-2-ethyl-N-benzyl-4,7,10,13-tetraoxa-8,9-benzo-1-azacyclopentadec-8-ene.NaClO4], has been prepared and studied by x-ray diffraction. The compound crystallizes in space group P2(1) with cell dimensions a = 8.721(1), b = 16.318(2), c = 8.905( 1) Angstrom, beta = 100.80(1)degrees. The sodium cation is heptacoordinated and located significantly out of the best plane of the macrocycle ring. The donor atoms of the macrocycle are in the half-chair arrangement.eninfo:eu-repo/semantics/closedAccessBenzo-Monoaza-15-Crown-5Chiral Crown EtherCrystal StructureSodium ComplexArticle451-2123128WOS:0001820060000192-s2.0-034459675410.1023/A:1023042119365Q2Q2