Önal, Halil İbrahimDurap, FeyyazAydemir, MuratZahmakiran, Mehmet2024-04-242024-04-242024Önal, H. İ., Durap, F., Aydemir, M. ve Zahmakiran, M. (2024). Highly active Pd nanoparticles decorated on benzene-ring doped g-C3N4 as catalyst in methylene Blue degradation and Cr (VI) ions reduction. Applied Organometallic Chemistry, 38(5), e74420268-26051099-0739https://doi.org/10.1002/aoc.7442https://hdl.handle.net/11468/13976https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.7442The development of simply prepared, highly active and reusable nanocatalysts for methylene blue degradation (MB) or Cr (VI) ions reduction under sunlight conditions in wastewater remains a challenge in the field of green chemistry. Addressed herein is the catalyst of Pd(0) nanoparticles supported on benzene ring doped graphitic carbon nitride (Pd@BD-g-C3N4) for MB degradation or Cr (VI) ions reduction under visible light irradiation. Pd@BD-g-C3N4 nanocatalyst has been synthesized using the facile wet impregnation-chemical reduction method to boost the catalytic efficiency of BD-g-C3N4. The MB degradation or Cr (VI) ions reduction proceeded efficiently in the presence of Pd@BD-g-C3N4. Compared with pure BD-g-C3N4 in both studies, the hybrid photocatalyst Pd@BD-g-C3N4-exhibited enhanced visible light photoactivity was higher than of pure BD-g-C3N4. In addition, in the reusability tests, it was observed that the Pd@BD-g-C3N4 photocatalyst has good stability and repeated cycle performance. The electronic and morphologic structure of support material and nanocatalyst were characterized by several techniques such as FT-IR, DR/UV-Vis, BET, SEM-EDX, HR-TEM, P-XRD, and XPS analyses.eninfo:eu-repo/semantics/openAccessBd-G-C3n4Cr (Vi) IonsMethylene bluePd NanoparticlesPhotocatalystHighly active Pd nanoparticles decorated on benzene-ring doped g-C3N4 as catalyst in methylene Blue degradation and Cr (VI) ions reductionHighly active Pd nanoparticles decorated on benzene-ring doped g-C3N4 as catalyst in methylene Blue degradation and Cr (VI) ions reductionArticle385WOS:0011872028000012-s2.0-8518850571310.1002/aoc.7442Q1N/A