Koylu, M. ZaferAral, TarikKarakaplan, MehmetKocakaya, Safak OzhanHosgoren, Halil2024-04-242024-04-2420111300-0527https://doi.org/10.3906/kim-1008-844https://search.trdizin.gov.tr/yayin/detay/114391https://hdl.handle.net/11468/19353In order to investigate the enantiomeric recognition abilities toward 2 chiral alkylammonium perchlorates (AmI, AmII) by H-1-NMR titration method in CDCl3, 4 chiral lariat ethers 8-11 with a (p-methoxyphenoxy) methyl flexible side arm were used. The most effective enantiomeric recognition was obtained by LCEs 9 and 11 toward AmII, by K-R/K-S 6.58 and K-S/K-R 6.63, respectively. The effect of macroring size, subunit of macroring, and side arm appeared to have strong influence on the binding ability of these alkylammonium ions.eninfo:eu-repo/semantics/openAccessChiral Lariat Crown EthersEnantioselectivityComplexation PropertiesMolecular RecognitionNmr TitrationEnantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchloratesEnantioselective complexation of chiral lariat crown ethers and chiral primary alkylammonium perchloratesArticle352171179WOS:00028809660000111439110.3906/kim-1008-844Q3