Synthesis and spectral studies of macrocyclic Cu(II) complexes by reaction of various diamines, copper(II) perchlorate and 1,4-bis(2-carboxyaldehyde phenoxy)butane
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Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Six macrocyclic complexes, were synthesized by reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane and various amines and their copper(II) perchlorate complexes were synthesized by template effect reaction of 1,4-bis(2-carboxyaldehyde phenoxy)butane, Cu(ClO4)2 center dot 6H(2)O and amines. The metal-to-ligand ratios were found to be 1 : 1. Cu(II) metal complexes are 1: 2 electrolytes as shown by their molar conductivities (Lambda(M)) in DM F (dimethyl formamide) at 10(-3) M. The Cu(II) complexes are proposed to be square planar based on elemental analysis, FT-IR, UV-Vis, magnetic susceptibility measurements, molar conductivity measurements, and mass spectra.
Açıklama
Anahtar Kelimeler
Macrocyclic Schiff-Base Complexes, 1,4-Bis(2-Carboxyaldehyde Phenoxy)Butane And Copper(Ii) Complexes
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
61
Sayı
2
