Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes

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dc.contributor.authorDurap, Feyyaz
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorAk, Bunyamin
dc.contributor.authorBaysal, Akin
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T16:15:15Z
dc.date.available2024-04-24T16:15:15Z
dc.date.issued2016
dc.departmentDicle Üniversitesien_US
dc.description.abstractKnown Ru(II), Rh(I) and Ir(III) complexes of C-2-symmetric ferrocenyl based chiral bis(phoshinite) ligands were catalyzed the asymmetric transfer hydrogenation of alkyl/aryl or alkyl methyl ketones. Corresponding secondary alcohols were obtained with high enantioselectivities up to 98% ee and reactivities using iso-propanol as the hydrogen source. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAK [111T419]en_US
dc.description.sponsorshipFinancial support from TUBITAK (Grant number: 111T419) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.jorganchem.2016.05.025
dc.identifier.endpage97en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84974603635
dc.identifier.scopusqualityQ2
dc.identifier.startpage92en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2016.05.025
dc.identifier.urihttps://hdl.handle.net/11468/15725
dc.identifier.volume818en_US
dc.identifier.wosWOS:000380751600013
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectC-2-Symmetryen_US
dc.subjectFerrocenyl Ligandsen_US
dc.subjectPhosphiniteen_US
dc.titleAsymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexesen_US
dc.titleAsymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes
dc.typeArticleen_US

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