Synthesis and characterization of transition metal complexes of thiophene-2-methylamine: X-ray crystal structure of palladium (II) and platinum (II) complexes and use of palladium(II) complexes as pre-catalyst in Heck and Suzuki cross-coupling reactions

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dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorGümgüm, Bahattin
dc.contributor.authorÖzkar, Saim
dc.contributor.authorYıldırım, Leyla Tatar
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2009
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe reactions of thiophene-2-(N-diphenylphosphino)methylamine, Ph2PNHCH2-C4H3S, 1 and thiophene-2-[N,N-bis(diphenylphosphino)methylamine], (Ph2P)(2)NCH2-C4H3S, 2, with MCl2(cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) or [Cu(CH3CN)(4)]PF6 yields the new complexes [M(Ph2PNHCH2-C4H3S)(2)Cl-2], M = Pd 1a, Pt 1 b, [Cu(Ph2PNHCH2-C4H3S)(4)]PF6, 1c, and [M(Ph2P)(2)NCH2-C4H3S)Cl-2], M = Pd 2a, Pt 2b, (Cu[(Ph2P)(2)NCH2-C4H3S](2))PF6, 2c, respectively. The new compounds were isolated as analytically pure crystalline solids and characterized by (31)p-, C-13-, H-1-NMR and IR spectroscopy and elemental analysis. Furthermore, the solid-state molecular structures of representative palladium and platinum complexes of bis(phosphine)amine, 2a and 2b, respectively, were determined using single crystal X-ray diffraction analysis. The palladium complexes were tested as potential catalysts in the Heck and Suzuki cross-coupling reactions. Copyright (C) 2009 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University [DUAPK 05-FF-27]en_US
dc.description.sponsorshipPartial support from Dicle University (project number DUAPK 05-FF-27) is gratefully acknowledged.en_US
dc.description.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.1547
dc.identifier.citationAydemir, M., Baysal, A., Durap, F., Gümgüm, B., Özkar, S. ve Yıldırım, L. T. (2009). Synthesis and characterization of transition metal complexes of thiophene-2-methylamine: X-ray crystal structure of palladium (II) and platinum (II) complexes and use of palladium(II) complexes as pre-catalyst in Heck and Suzuki cross-coupling reactions. Applied Organometallic Chemistry, 23(11), 467-475.
dc.identifier.doi10.1002/aoc.1547
dc.identifier.endpage475en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-70350153780
dc.identifier.scopusqualityQ1
dc.identifier.startpage467en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1547
dc.identifier.urihttps://hdl.handle.net/11468/13955
dc.identifier.volume23en_US
dc.identifier.wosWOS:000271513900006
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectBis(phosphino)amineen_US
dc.subjectPalladiumen_US
dc.subjectHeck reactionen_US
dc.subjectSuzuki couplingen_US
dc.titleSynthesis and characterization of transition metal complexes of thiophene-2-methylamine: X-ray crystal structure of palladium (II) and platinum (II) complexes and use of palladium(II) complexes as pre-catalyst in Heck and Suzuki cross-coupling reactionsen_US
dc.titleSynthesis and characterization of transition metal complexes of thiophene-2-methylamine: X-ray crystal structure of palladium (II) and platinum (II) complexes and use of palladium(II) complexes as pre-catalyst in Heck and Suzuki cross-coupling reactions
dc.typeArticleen_US

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