Novel half-sandwich η5-Cp *-rhodium(III) and η5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketones
Yükleniyor...
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Two new half-sandwich (5)-Cp*-rhodium(III) and (5)-Cp*-ruthenium(II) complexes have been prepared from corresponding bis(phosphino)amine ligands, thiophene-2-(N,N-bis(diphenylphosphino)methylamine) or furfuryl-2-(N,N-bis(diphenylphosphino)amine). Structures of the new complexes have been elucidated by multinuclear one- and two-dimensional NMR spectroscopy, elemental analysis and IR spectroscopy. These Cp*-rhodium(III) and Cp*-ruthenium(II) complexes bearing bis(phosphino)amine ligands were successfully applied to transfer hydrogenation of various ketones by 2-propanol. Copyright (c) 2013 John Wiley & Sons, Ltd.
Açıklama
Anahtar Kelimeler
Bis(Phosphino)Amine, Cp*, Rhodium, Ruthenium, Transfer hydrogenation
Kaynak
Applied Organometallic Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
28
Sayı
1
Künye
Ok, F., Aydemir, M., Durap, F. ve Baysal, A. (2014). Novel half-sandwich η5-Cp *-rhodium(III) and η5-Cp *-ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation of aromatic ketones. Applied Organometallic Chemistry, 28(1), 38-43.
