Synthesis of novel chiral Schiff-base ligands and their application in asymmetric nitro aldol (Henry) reaction

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dc.contributor.authorColak, Mehmet
dc.contributor.authorAral, Tarik
dc.contributor.authorHosgoeren, Halil
dc.contributor.authorDemirel, Nadir
dc.date.accessioned2024-04-24T16:18:27Z
dc.date.available2024-04-24T16:18:27Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractChiral Schiff-bases prepared from chiral amino alcohols catalyze the enantio selective Henry (nitro aldol) reaction between nitromethane and p-nitrobenzaldehyde in the presence of Cu(OTf)(2) and Zn(OTf)(2). Zn(OTf)(2) promoted the reaction yield, while Cu(OTf)(2) promoted the enantiomeric excess. The highest enantioselectivities were observed with ligand 3 (44% ee) and ligand 5 (47% ee). (C) 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.tetasy.2007.04.025
dc.identifier.endpage1133en_US
dc.identifier.issn0957-4166
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-34249894998
dc.identifier.scopusqualityN/A
dc.identifier.startpage1129en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetasy.2007.04.025
dc.identifier.urihttps://hdl.handle.net/11468/16100
dc.identifier.volume18en_US
dc.identifier.wosWOS:000247898000015
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron-Asymmetry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis of novel chiral Schiff-base ligands and their application in asymmetric nitro aldol (Henry) reactionen_US
dc.titleSynthesis of novel chiral Schiff-base ligands and their application in asymmetric nitro aldol (Henry) reaction
dc.typeArticleen_US

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