The effect of gamma radiation on some succinic acid derivatives in the solid state
[ X ]
Tarih
2017
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Bv
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
2,2-dimethyl succinic acid, 2,3-dimethyl succinic acid and monomethyl succinate were exposed to gamma radiation in the form of powder. EPR measurements were carried out to investigate the free radicals produced in all of them, following irradiation. Three of the radical species formed after irradiation were identified and spectroscopic parameters were discussed thereafter. The radical species were attributed to the (C) over dotHCH(2), HOOCCH(CH3)(2)(C) over dotCOOH and H3COOCCH2(C) over dotHCOOH radicals, respectively. The hyperfine splitting constants for all radicals were confirmed by the simulation of the experimental spectra. The radiation sensitivity of the samples was mainly attributed to the EPR line properties of stable radicals. (C) 2016 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Epr, Free Radicals, Succinic Acid Derivatives, Gamma Irradiation
Kaynak
Journal of Molecular Structure
WoS Q Değeri
Q3
Scopus Q Değeri
Q1
Cilt
1127
