Crystal structure of rac-3-hydroxy-2-(p-tolyl)-2,3,3a, 4,7,7a-hexahydro-1H-4,7-methanoisoindol-1-one
[ X ]
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Int Union Crystallography
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In the title compound, C16H17NO2, the cyclohexene ring adopts a boat conformation, and the five-membered rings have envelope conformations with the bridging atom as the flap. Their mean planes are oriented at a dihedral angle of 86.51 (7)degrees. The molecular structure is stabilized by a short intramolecular C-H center dot center dot center dot O contact. In the crystal, molecules are linked by O-H center dot center dot center dot O hydrogen bonds forming chains propagating along [100]. The chains are linked by C-H center dot center dot center dot pi interactions, forming slabs parallel to (001).
Açıklama
Anahtar Kelimeler
Crystal Structure, Methanoisoindol-1-One, Methanoisoindole-1,3-Dione, O-H Center Dot Center Dot Center Dot O Hydrogen Bonds, C-H Center Dot Center Dot Center Dot Pi Interactions
Kaynak
Acta Crystallographica Section E-Crystallographic Communications
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
71
