Synthesis, characterization and redox properties of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,3-bis(2-carboxyaldehyde phenoxy) propane and its CuII, NiII, PbII, CoIII and LaIII complexes

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dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorYilmaz, Ismail
dc.contributor.authorKilic, Ahmet
dc.date.accessioned2024-04-24T16:02:22Z
dc.date.available2024-04-24T16:02:22Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new macrocyclic ligand, 1,3,5-triaza-2,4:7,8:, 14,15-tribenzo-9,13-dioxacyclohexadeca-1,5-diene ( L) was synthesized by reaction of 2,6-diaminopyridine and 1,3-bis(2-carboxyaldehyde phenoxy) propane. Then, its Cu-II, Ni-II, Pb-II, Co-III and La-III complexes were synthesized by a template effect by reaction of 2,6-diaminopyridine and 1,3-bis (2-carboxyaldehyde phenoxy) propane and Cu(NO3)(2) center dot 3H(2)O, Ni(NO3)(2) center dot 6H(2)O, Co(NO3)(2) center dot 6H(2)O, La(NO3)(3) center dot 6H(2)O, respectively. The ligand and its metal complexes have been characterized by elemental analysis, IR, H-1- and C-13-NMR-, UV-vis spectra, magnetic susceptibility, conductivity measurements, mass spectra and cyclic voltammetry. All complexes are diamagnetic and the Cu-II complex is binuclear. The diamagnetic behaviour of the binuclear complex may be explained by a very strong anti-ferromagnetic interaction in the Cu-Cu pair. The Co-II was oxidised to Co-III.en_US
dc.identifier.doi10.1007/s11243-006-0174-2
dc.identifier.endpage349en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-34247155395
dc.identifier.scopusqualityQ2
dc.identifier.startpage344en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-006-0174-2
dc.identifier.urihttps://hdl.handle.net/11468/14763
dc.identifier.volume32en_US
dc.identifier.wosWOS:000245704700008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis, characterization and redox properties of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,3-bis(2-carboxyaldehyde phenoxy) propane and its CuII, NiII, PbII, CoIII and LaIII complexesen_US
dc.titleSynthesis, characterization and redox properties of macrocyclic Schiff base by reaction of 2,6-diaminopyridine and 1,3-bis(2-carboxyaldehyde phenoxy) propane and its CuII, NiII, PbII, CoIII and LaIII complexes
dc.typeArticleen_US

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