Complexation and mutagenicity potential studies with N,N?-bis(2-hydroxynaphthalin-1-carbaldehydene)-1,2-bis-(P-aminophenoxy)ethane and a novel oxovanadium(IV) complex
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Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A new oxovanadium(IV) complex of the Schiff base obtained by condensation of 1,2-bis(p-aminophenoxy)ethane with 2-hydroxynaphthalin-1-carbaldehyde was synthesized. The complex was characterized by elemental analysis, magnetic measurements, mass spectral data, UV-visible and IR spectra. Stability constants and thermodynamic values for complexation between Cu(NO3)(2), Zn(NO3)(2) (.) 6H(2)O, Ni(NO3)(2) (.) 6H(2)O and VOSO4 (.) 5H(2)O and the ligand in 80% dioxane/water were determined by conductance measurements. Ni(II) and Cu(II) complexes of the ligand synthesized by a previously described method were found to be mutagens on strain TA 100 in the presence and absence of S9 mix. These compounds are classified as mutagenic in the Ames test.
Açıklama
Anahtar Kelimeler
Schiff-Base Complexes, Complexation Studies, Mutagenic And Ames Test, Oxovanadium(Iv)
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
57
Sayı
7
