Electron paramagnetic resonance of ?-irradiated glycyl-L-glutamine monohydrate, iminodiacetic acid and methyliminodiacetic acid
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Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The electron paramagnetic resonances of gamma-irradiated powders of glycyl- L- glutamine monohydrate, iminodiacetic acid and methyliminodiacetic acid were investigated at room temperature. The observed species in glycyl- L- glutamine monohydrate powders were attributed to the CH2<(C)over dot>NHCOOH radical; and those in iminodiacetic acid and methyliminodiacetic acid powders to the HN<(C)over dot>HCH2(COOH)(2) and H3CN<(C)over dot>HCH2(COOH)(2) radicals respectively. The spectra were computer simulated and the g values of the radicals and the hyperfine structure constants of the unpaired electron with nearby protons and N-14 nucleus were determined. The results were found to be in good agreement with the existing literature data.
Açıklama
Anahtar Kelimeler
Epr, Free Radicals, Gamma Irradiation, Amino Acid, Iminodiacetic Acid Derivatives
Kaynak
Radiation Effects and Defects in Solids
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
163
Sayı
1