Synthesis of R-(-)-2-ethyl-N-benzyl (monoaza-15-crown-5) and the crystal structure of its sodium perchlorate complex

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dc.contributor.authorÖzbey, S
dc.contributor.authorHosgören, H
dc.contributor.authorTurgut, Y
dc.contributor.authorTopal, G
dc.date.accessioned2024-04-24T16:19:09Z
dc.date.available2024-04-24T16:19:09Z
dc.date.issued2001
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new complex of a chiral monoaza-crown ether, [R-(-)-2-ethyl-N-benzyl-4,7,10,13-tetraoxa-1-azacyclopentadeceane) NaClO4], has been prepared and studied by x-ray diffraction. The compound crystallizes in space group P2(1) with cell dimensions a = 9.480(1), b = 15.978(2), c = 15.816(2) Angstrom, beta = 105.51(1)degrees, Z = 4. The final R value is 0.055 for 2711 observed reflections and 540 parameters. There are two molecules in the asymmetric unit labelled A and B. The sodium ion is hexacoordinated. The average values for the Na-O-eth (etheric) distances are 2.364(6), 2.317(7) Angstrom and the Na-N distances are 2.679(6), 2.611(7) Angstrom; the Na-O(ClO4) contacts are 2.497(7) and 2.257(10) Angstrom, for A and B, respectively.en_US
dc.identifier.doi10.1023/A:1011193009853
dc.identifier.endpage320en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue3-4en_US
dc.identifier.scopus2-s2.0-0041538226
dc.identifier.scopusqualityQ2
dc.identifier.startpage315en_US
dc.identifier.urihttps://doi.org/10.1023/A:1011193009853
dc.identifier.urihttps://hdl.handle.net/11468/16415
dc.identifier.volume39en_US
dc.identifier.wosWOS:000167932100018
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChiral Crown Etheren_US
dc.subjectCrystal Structureen_US
dc.subjectMonoaza-15-Crown-5en_US
dc.subjectSodium Complexen_US
dc.titleSynthesis of R-(-)-2-ethyl-N-benzyl (monoaza-15-crown-5) and the crystal structure of its sodium perchlorate complexen_US
dc.titleSynthesis of R-(-)-2-ethyl-N-benzyl (monoaza-15-crown-5) and the crystal structure of its sodium perchlorate complex
dc.typeArticleen_US

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