Benzylation of benzene and toluene with benzylchloride over clay-based acid catalysts

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dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAkcay, Mehmet
dc.contributor.authorYurdakoc, Kadir
dc.date.accessioned2024-04-24T17:33:17Z
dc.date.available2024-04-24T17:33:17Z
dc.date.issued2006
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe pillared clay catalysts were calcined after in corporation of metal polycation ions with exchangeable cations and water. Friedel-Crafts alkylations of aromatic hydrocarbons were carried out in the presence of clay catalysts originating from bentonite. In these reactions, it has been found that pillared clays have excellent catalytic activity. It was found that iron pillared clay (Fe-PILC) was the more efficient catalyst producing quantitative conversion with greatly reduced amounts of catalysts in short reaction period. Their efficiency is attributed to the higher Fe3+, Cr3+ and Al3+ contents in the catalysts and pillaring effect. The clays have both Bronsted and Lewis acidities which were determined by pyridine adsorption-desorption and in situ FTIR technique.en_US
dc.identifier.endpage1807en_US
dc.identifier.issn0970-7077
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-33745818932
dc.identifier.scopusqualityQ4
dc.identifier.startpage1803en_US
dc.identifier.urihttps://hdl.handle.net/11468/20586
dc.identifier.volume18en_US
dc.identifier.wosWOS:000238892000026
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherMrs Pushpa Agarwalen_US
dc.relation.ispartofAsian Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectFriedel-Crafts Alkylationen_US
dc.subjectBentoniteen_US
dc.subjectPillared Claysen_US
dc.subjectSurface Acidityen_US
dc.titleBenzylation of benzene and toluene with benzylchloride over clay-based acid catalystsen_US
dc.titleBenzylation of benzene and toluene with benzylchloride over clay-based acid catalysts
dc.typeArticleen_US

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